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Coulometry Articles & Analysis

6 articles found

Karl Fischer titration: When to use volumetry or coulometry

Karl Fischer titration: When to use volumetry or coulometry

To begin, the main difference between volumetry and coulometry is discussed: the «addition» of the ...

ByB&W Tek


Side reactions in Karl Fischer titration

Side reactions in Karl Fischer titration

Many chemists that utilize Karl Fischer titration are nervous about the presence of side reactions because they know that the water determination in their samples can only be specific without any side reactions. Other KFT users do not know what the possible side reactions are and therefore may obtain incorrect ...

ByMetrohm AG


Reliable Elemental Analysis for Nitrogen, Sulfur, and Chlorine in Biofuels

Reliable Elemental Analysis for Nitrogen, Sulfur, and Chlorine in Biofuels

A multi EA 5100 was used in horizontal operating mode, equipped with HiPerSens detectors, UVFD for sulfur detection, chemiluminescence detection (CLD) for nitrogen, and coulometry for chlorine. For automated sampling and the transfer of the samples and standards to the analyzer, the system was equipped with an automatic boat drive (ABD), including a flame sensor and a ...

ByAnalytik Jena - Lab-loving people


Best practice for electrodes in Karl Fischer titration

Best practice for electrodes in Karl Fischer titration

As the indicator electrode detects the endpoint, you can imagine that the results depend highly on the condition of the electrode. In coulometry, an additional electrode (generator electrode) is used to generate the iodine needed for the titration. ...

ByMetrohm AG


Double potential step chronocoulometric studies to determine the role of thiocyanate in electroanalytical determination of gallium in Pu–Ga and U–Ga alloys

Double potential step chronocoulometric studies to determine the role of thiocyanate in electroanalytical determination of gallium in Pu–Ga and U–Ga alloys

Two rapid, selective and simple methods are developed for the determination of gallium in Pu–Ga and U–Ga alloys using Anodic Stripping Voltammetry (ASV) and Controlled Potential Coulometry (CPC). In continuation of this work, a detailed study is presented to determine the role of SCN− during the determination of gallium at Static Mercury Drop Electrode (SMDE) in NaClO4 and NaSCN ...

ByInderscience Publishers


Double potential step chronocoulometric studies to determine the role of thiocyanate in electroanalytical determination of gallium in Pu-Ga and U-Ga alloys

Double potential step chronocoulometric studies to determine the role of thiocyanate in electroanalytical determination of gallium in Pu-Ga and U-Ga alloys

Two rapid, selective and simple methods are developed for the determination of gallium in Pu-Ga and U-Ga alloys using Anodic Stripping Voltammetry (ASV) and Controlled Potential Coulometry (CPC). In continuation of this work, a detailed study is presented to determine the role of SCN− during the determination of gallium at Static Mercury Drop Electrode (SMDE) in NaClO4 and ...

ByInderscience Publishers

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